ASTM D4737-04

The Calculated Cetane Index by Four Variable Equation is useful for estimating ASTM cetane number when a test engine is not available for determining this property directly and when cetane improver is not used. It may be conveniently employed for estimating cetane number when the quantity of sample available is too small for an engine rating. In cases where the ASTM cetane number of a fuel has been previously established, the Calculated Cetane Index by Four Variable Equation is useful as a cetane number check on subsequent batches of that fuel, provided the fuel’source and mode of manufacture remain unchanged.

Within the range from 32.5 to 56.5 cetane number, the expected error of prediction of Procedure A of the Calculated Cetane Index by Four Variable Equation will be less than ±2 cetane numbers for 65 % of the distillate fuels evaluated. Errors may be greater for fuels whose properties fall outside the recommended range of application.

1.1 The calculated Cetane Index by Four Variable Equation provides a means for estimating the ASTM cetane number (Test Method D 613) of distillate fuels from density and distillation recovery temperature measurements. The value computed from the equation is termed the Calculated Cetane Index by Four Variable Equation.

1.2 The Calculated Cetane Index by Four Variable Equation is not an optional method for expressing ASTM cetane number. It is a supplementary tool for estimating cetane number when a result by Test Method D 613 is not available and if cetane improver is not used. As a supplementary tool, the Calculated Cetane Index by Four Variable equation must be used with due regard for its limitations.

1.3 Procedure A is to be used for Specification D 975, Grades No. 1-D Low Sulfur, No. 1-D, No. 2-D, and No. 4-D. This method for estimating cetane number was developed by Chevron Research Co. Procedure A is based on a data set including a relatively small number of No. 1-D fuels. Test Method D 4737 may be less applicable to No.1-D, No. 1-D Low Sulfur and No. 4-D grades than to No. 2-D grade.

1.4 Procedure B is to be used for Specification D 975, Grade No. 2-D Low Sulfur.

1.5 The test method "Calculated Cetane Index by Four Variable Equation" is particularly applicable to Grade 1-D, Grade No. 1-D Low Sulfur and Grade 2-D diesel fuel oils containing straight-run and cracked stocks, and their blends. It can also be used for heavier fuels with 90 % recovery points less than 382C and for fuels containing derivatives from oil sands and oil shale.

1.6 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information only.

1.7 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.