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Standard Test Method for Conducting Aqueous Direct Photolysis Tests (Withdrawn 2013) (Includes all amendments And changes 3/18/2013).
Automatische name übersetzung:
Standard Test Method for Durchführung Wässrige direkten Photolyse Tests (Withdrawn 2013)
NORM herausgegeben am 1.8.2005
Bezeichnung normen: ASTM E896-92(2005)e1
Anmerkung: UNGÜLTIG
Ausgabedatum normen: 1.8.2005
SKU: NS-48395
Zahl der Seiten: 8
Gewicht ca.: 24 g (0.05 Pfund)
Land: Amerikanische technische Norm
Kategorie: Technische Normen ASTM
Keywords:
ICS Number Code 71.040.50 (Physicochemical methods of analysis)
Significance and Use | ||||
For some materials, photolysis is one of the most significant means of transformation in the environment. These photolysis tests provide a means of estimating rates of natural phototransformation of a material in the environment. Determination of phototransformation products may provide insight into possible effects of the material on the environment and suggest areas for ecological effects tests. Photolysis tests assist in the decision-making process necessary for an exposure assessment program. |
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1. Scope | ||||
1.1 This test method describes procedures for obtaining information on direct photolysis rates, quantum yields, and phototransformation products of materials in an aqueous environment. Laboratory testing procedures designed to provide estimates of environmental rates of photolysis are described. 1.2 A three-tiered approach is described. The testing procedures are designed to provide basic and easily obtainable information in the first tier. More detailed and costly experiments are proposed in the second and third tiers. This approach is thought to be more scientific and cost-effective than one which provides for no sequential assessment. It is not within the scope of this test method to provide decision points to move from one tier to the next. The degree of testing should be decided as part of an overall exposure assessment in which the importance of photolysis is weighed with respect to other transformation routes. 1.3 These procedures are designed to be applicable to all types of materials. However, tests on formulations and commercial products that are complex mixtures of materials with diverse physical and chemical properties may require isolation of individual compounds prior to testing to eliminate indirect photochemical reactions. With slight modification, these procedures should meet the needs of most investigators. 1.4 In developing this test method an attempt was made to balance the needs and costs against the scientific considerations and reliability of results. Major considerations were: (1) that the procedures generate precise, accurate, and environmentally relevant data, and (2) that the procedural requirements be as flexible as possible without destroying this integrity of the data and the ability to compare interlaboratory results. 1.5 Since all details are not covered in this test method, successful execution of the described tests will require some training or experience in the area of photolysis. Familiarity with the material in the references is essential. Detailed descriptions on conducting similar test procedures have been published by the U.S. Environmental Protection Agency (1, 2). 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Section 6. |
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2. Referenced Documents | ||||
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